In order to improve the penetration performance of shaped charge liner, the charge structure of segmental shaped charge liner was designed, and its high efficiency damage characteristics were studied. Aiming at the concrete target, the comparative experimental study on the penetration of various active material and structure liners was carried out, and the damage effect of the active material liner was analyzed. Based on the test results and analysis, the liner material and structure design are optimized. The results show that the study provides a reference for the engineering application of active material liner.